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Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 15-23 doi: 10.1007/s11705-022-2177-8

摘要： Recently, various semiconductor/metal composites have been developed to fabricate surface-enhanced Raman spectroscopy substrates. However, low metal loading on semiconductors is still a challenge. In this study, cystine was introduced to increase the accumulation of gold nanoparticles on zinc oxide, owing to the biomineralization property of cystine. Morphological analysis revealed that the obtained ZnO/Au/cystine composite not only had a higher metal loading but also formed a porous structure, which is beneficial for Raman performance. Compared with ZnO/Au, the ZnO/Au/cystine substrate displayed a 40-fold enhancement in the Raman signal and a lower limit of detection (10–11 mol·L−1) in the detection of rhodamine 6G. Moreover, the substrate has favorable homogeneity and stability. Finally, ZnO/Au/cystine displayed excellent performance toward crystal violet and methylene blue in a test based on river water samples. This study provided a promising method to fabricate sensitive semiconductor/noble metal-based surface-enhanced Raman spectroscopy substrates for Raman detection.

关键词： biomineralization     cystine     semiconductor/metal composite     SERS detection     Raman detection    

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Chemical mapping of cement pastes by using confocal Raman spectroscopy

Fengjuan LIU,Zhihui SUN

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 168-173 doi: 10.1007/s11709-015-0323-9

摘要： In the present study, chemical mapping on the hydration process of cement paste with water-to-cement ( / ) ratio of 0.60 was implemented by Raman spectroscopy (RS). The RS was applied to study the paste from 12 hours after mixing to 28 days. Cement ingredients and hydration products, including calcium silicates (C S and C S), calcium hydroxide (CH), and ettringite, were quantitatively studied. From the research, it is observed that calcium silicates were consumed gradually with the increased hydration age. Calcium hydroxide increased and tended to cluster in the pore vicinity during hydration. Ettringite was found to form on the surface of the unreacted particles, which was shown as a mixed zone of ettringite and calcium silicates in the maps. It is concluded from the study that chemical mapping was an effective method to assist in visualizing particle dispersion and connection on top of the quantitative analysis.

关键词： chemical mapping     Raman spectroscopy     calcium silicates     calcium hydroxide     ettringite    

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V-shaped substrate for surface and volume enhanced Raman spectroscopic analysis of microplastics

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1578-8

摘要：

● V-shaped substrate was obtained for SERS analysis of microplastics (diameter ≈ 1 μm).

关键词： SERS     V-shaped     AAO     Microplastic     Atmospheric aerosol    

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Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

《能源前沿（英文）》 2019年 第13卷 第1期   页码 163-171 doi: 10.1007/s11708-018-0554-2

摘要： This paper focuses on the superiority of organic-inorganic hybrid ion-gel electrolytes for lithium-ion batteries (LiBs) over commercial electrolytes, such as 1 M LiPF in 1:1 ethylene carbonate (EC): dimethyl carbonate (DMC) {1 M LiPF -EC: DMC}, in terms of their flame susceptibility. These ion-gel electrolytes possess ionic liquid monomers, which are confined within the borosilicate or silicate matrices that are ideal for non-flammability. Naked flame tests confirm that the organic-inorganic hybrid electrolytes are less susceptible to flames, and these electrolytes do not suffer from a major loss in terms of weight. In addition, the hybrids are self-extinguishable. Therefore, these hybrids are only oxidized when subjected to a flame unlike other commercial electrolytes used in lithium-ion batteries. Supplementary analyses using differential scanning calorimetric studies reveal that the hybrids are glassy until the temperature reaches more than 100°C. The current results are consistent with previously published data on the organic-inorganic hybrids.

关键词： inorganic polymeric borosilicate network     organic-inorganic hybrids     self-extinguishability     nonflammability     lithium batteries     flame-retardants    

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Solar photovoltaic fed dual input LED lighting system with constant illumination control

Kinattingal SUNDARESWARAN,Kevin Ark KUMAR,Payyalore Raman VENKATESWARAN,Sankaran PALANI

《能源前沿（英文）》 2016年 第10卷 第4期   页码 473-478 doi: 10.1007/s11708-016-0420-z

摘要： A dual input LED lighting scheme with constant illumination is proposed in this paper. The scheme employs a photovoltaic array as the first input and a battery as the second one. A microcontroller is programmed to operate a changeover switch as well as a DC-DC converter for uninterrupted and constant illumination in work place. The scheme is suitable for conference halls, laboratories, clean rooms, marriage halls, theaters, etc. The complete modeling, design and experimentation of the proposed scheme are explained and the economic viability of the scheme is justified.

关键词： photovoltaic     LED light     dual input     P&O algorithm    

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Ternary phase behavior of water microemulsified diesel-palm biodiesel

Nurul Atiqah Izzati MD ISHAK,Ismail Ab RAMAN,Mohd Ambar YARMO,Wan Mohd Faizal WAN MAHMOOD

《能源前沿（英文）》 2015年 第9卷 第2期   页码 162-169 doi: 10.1007/s11708-015-0355-9

摘要： This paper aims to develop a new microemulsions system comprising diesel and palm oil methyl ester (PME) that have the potential to be used as alternative fuels for diesel engines. The water-in-diesel-biodiesel microemulsions were prepared by applying PME mixed with diesel, non-ionic surfactants, co-surfactants and water to make the water-in-oil (W/O) microemulsion system. This microemulsified fuel was achieved through low-energy microemulsification by using the constant composition method. The diesel used was mixed with four different concentrations of PME, i.e., 10% (w/w) (B10), 20% (w/w) (B20), 30% (w/w) (B30) and neat diesel (B0). The amount of water was fixed at 20% (w/w). The phase behavior of the water/mixed non-ionic surfactant/diesel-PME system were studied by constructing pseudoternary phase diagrams with the goal of formulating optimized systems. The results showed that the microemulsions were formed and stabilized with a mixture of non-ionic surfactants at a weight ratio of 80:20 at 20% (w/w), and with mixed co-surfactants at a weight ratio of 25:75, 20:80 and 10:90 for B0, B10, B20 and B30 respectively. The particle size, kinematic viscosity at 40°C, refractive index, density, heating value, cloud point, pour point and flash point of the selected water-in-diesel microemulsion were 19.40 nm (polydispersity of 0.12), 2.86 mm /s, 1.435, 0.8913 g/mL, 31.87 MJ/kg, 7.15°C, 10.5°C and 46.5°C respectively. The corresponding values of the water-in-diesel-PME selected were 20.72 nm to 23.74 nm, 13.02 mm /s to 13.29 mm /s, 1.442, 0.8939 g/mL to 0.8990 g/mL, 31.45 MJ/kg to 27.34 MJ/kg, 7.2°C to 6.8°C, 8.5°C to 1.5°C and 47.5°C to 52.0°C. These preliminary findings were further studied as potential fuels for diesel engines.

关键词： palm methyl ester     palm oil biodiesel     microemulsion     water microemulsified fuels    

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Large deflection behavior effect in reinforced concrete columns exposed to extreme dynamic loads

MUTALIB, Chunwei ZHANG, Javad MEHRMASHHADI, Sudharshan Naidu RAMAN, Roozbeh ALIPOUR, Tohid MOMENI, Mohamed

《结构与土木工程前沿（英文）》 2020年 第14卷 第2期   页码 532-553 doi: 10.1007/s11709-020-0604-9

摘要： Reinforced concretes (RC) have been widely used in constructions. In construction, one of the critical elements carrying a high percentage of the weight is columns which were not used to design to absorb large dynamic load like surface bursts. This study focuses on investigating blast load parameters to design of RC columns to withstand blast detonation. The numerical model is based on finite element analysis using LS-DYNA. Numerical results are validated against blast field tests available in the literature. Couples of simulations are performed with changing blast parameters to study effects of various scaled distances on the nonlinear behavior of RC columns. According to simulation results, the scaled distance has a substantial influence on the blast response of RC columns. With lower scaled distance, higher peak pressure and larger pressure impulse are applied on the RC column. Eventually, keeping the scaled distance unchanged, increasing the charge weight or shorter standoff distance cause more damage to the RC column. Intensive studies are carried out to investigate the effects of scaled distance and charge weight on the damage degree and residual axial load carrying capacity of RC columns with various column width, longitudinal reinforcement ratio and concrete strength. Results of this research will be used to assessment the effect of an explosion on the dynamic behavior of RC columns.

关键词： RC column     scaled distance     blast load     LS-DYNA    

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SERS nanoprobes for bio-application

Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong

《化学科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 428-441 doi: 10.1007/s11705-015-1536-0

摘要： The ability to tune the size, shape, composition and surface properties impart nanoparticles with the desired functions for bio-application. This article highlights some of the recent examples in the exploration of metal (e.g., gold and silver) nanoparticles, especially those with magnetic properties and bio-conjugated structures, as theranostic nanoprobes. Such nanoprobes exhibit tunable optical, spectroscopic, magnetic, and electrical properties for signal amplifications. Examples discussed in this article will focus on the nanoproble-enhanced colorimetric detection and surface enhanced Raman scattering (SERS) detection of biomarkers or biomolecules such as proteins and DNAs. The understanding of factors controlling the biomolecular interactions is essential for the design of SERS nanoprobes with theranostic functions.

关键词： surface-enhanced Raman scattering     functional nanoprobes     bio-conjugation     metal nanoparticles     magnetic properties     theranostic materials    

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Polymorphism and crystal transformation of penicillin sulfoxide

Dingding JING, Yongli WANG, Zhijian CHEN, Lina ZHOU, Jingkang WANG

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 442-447 doi: 10.1007/s11705-011-1140-x

摘要： Penicillin sulfoxide is the intermediate for the synthesis of 7-amino-3-desacetoxycephalosporanic acid which is one of the most important nucleuses of cephalosporin antibiotic. In this contribution, two crystal structures of penicillin sulfoxide (forms I and II) were determined by X-ray diffraction, and their thermotropic properties were investigated by differential scanning calorimetry (DSC). Furthermore, the transformation of form II to form I was studied quantitatively by Raman spectroscopy, and its rates at different temperatures were determined. The results indicate that penicillin sulfoxide is more stable as form I, and the temperature plays an important role in the crystal transformation.

关键词： penicillin sulfoxide     crystallization     polymorphism     crystal transformation     Raman spectroscopy    

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Usability perceptions and beliefs about smart thermostats by chi-square test, signal detection theory, and fuzzy detection theory in regions of Mexico

Pedro PONCE, Therese PEFFER, Arturo MOLINA

《能源前沿（英文）》 2019年 第13卷 第3期   页码 522-538 doi: 10.1007/s11708-018-0562-2

摘要： It is well known that smart thermostats (STs) have become key devices in the implementation of smart homes; thus, they are considered as primary elements for the control of electrical energy consumption in households. Moreover, energy consumption is drastically affected when the end users select unsuitable STs or when they do not use the STs correctly. Furthermore, in future, Mexico will face serious electrical energy challenges that can be considerably resolved if the end users operate the STs in a correct manner. Hence, it is important to carry out an in-depth study and analysis on thermostats, by focusing on social aspects that influence the technological use and performance of the thermostats. This paper proposes the use of a signal detection theory (SDT), fuzzy detection theory (FDT), and chi-square (CS) test in order to understand the perceptions and beliefs of end users about the use of STs in Mexico. This paper extensively shows the perceptions and beliefs about the selected thermostats in Mexico. Besides, it presents an in-depth discussion on the cognitive perceptions and beliefs of end users. Moreover, it shows why the expectations of the end users about STs are not met. It also promotes the technological and social development of STs such that they are relatively more accepted in complex electrical grids such as smart grids.

关键词： thermostats     perceptions     beliefs     signal detection theory (SDT)     fuzzy signal detection theory (FSDT)     chi-square (CS) test    

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Advances in airborne microorganisms detection using biosensors: A critical review

《环境科学与工程前沿（英文）》 2021年 第15卷 第3期 doi: 10.1007/s11783-021-1420-8

摘要：

Humanity has been facing the threat of a variety of infectious diseases. Airborne microorganisms can cause airborne infectious diseases, which spread rapidly and extensively, causing huge losses to human society on a global scale. In recent years, the detection technology for airborne microorganisms has developed rapidly; it can be roughly divided into biochemical, immune, and molecular technologies.

关键词： Biosensor     Airborne microorganisms     Microbiological detection technology    

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Recent advances in SERS detection of perchlorate

Jumin Hao, Xiaoguang Meng

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 448-464 doi: 10.1007/s11705-017-1611-9

摘要： Perchlorate has recently emerged as a widespread environmental contaminant of healthy concern. Development of novel detection methods for perchlorate with the potential for field use has been an urgent need. The investigation has shown that surface-enhanced Raman scattering (SERS) technique has great potential to become a practical analysis tool for the rapid screening and routine monitoring of perchlorate in the field, particularly when coupled with portable/handheld Raman spectrometers. In this review article, we summarize progress made in SERS analysis of perchlorate in water and other media with an emphasis on the development of SERS substrates for perchlorate detection. The potential of this technique for fast screening and field testing of perchlorate-contaminated environmental samples is discussed. The challenges and possible solutions are also addressed, aiming to provide a better understanding on the development directions in the research field.

关键词： perchlorate     SERS     detection     substrate     modification     nanostructure    

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A fast antibiotic detection method for simplified pretreatment through spectra-based machine learning

《环境科学与工程前沿（英文）》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1472-9

摘要：

• A spectral machine learning approach is proposed for predicting mixed antibiotic.

关键词： Antibiotic contamination     Spectral detection     Machine learning    

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脉冲辐射探测技术

欧阳晓平

《中国工程科学》 2008年 第10卷 第4期   页码 44-55

摘要：

脉冲辐射探测是探知核反应过程特征信息的主要途径之一，是核反应过程特性研究、核装置设计、运行、监测与控制不可或缺的技术手段。由核探测器、探测方法和应用技术等构成的脉冲辐射场探测技术，已成为科学研究、核技术应用、核材料分析、裂变/聚变研究和天体物理等相关核科学研究的必备技术元素。文章介绍了我国发展的瞬态核裂变、核聚变反应过程释放的脉冲中子、伽马混合辐射场探测系统和测量技术。

关键词： 裂变反应     聚变反应     脉冲辐射探测     探测系统     中子测量     伽马测量    

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Edge detection of steel plates at high temperature using image measurement

Qiong Zhou, Qi An

《机械工程前沿（英文）》 2009年 第4卷 第1期   页码 77-82 doi: 10.1007/s11465-009-0013-1

摘要： An edge detection method for the measurement of steel plate’s thermal expansion is proposed in this paper, where the shrinkage of a steel plate is measured when temperature drops. First, images are picked up by an imaging system; a method of regional edge detection based on grayscales’ sudden change is then applied to detect the edges of the steel plate; finally, pixel coordinates of the edge position are transformed to physical coordinates through calibration parameters. The experiment shows that the real-time, high precision, and non-contact measurement of the steel plate’s edge position under high temperature can be realized using the imaging measurement method established in this paper.

关键词： thermal expansion     image measurement     edge detection     image calibration    

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标题 作者 时间 类型 操作

Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman

期刊论文

Chemical mapping of cement pastes by using confocal Raman spectroscopy

Fengjuan LIU,Zhihui SUN

期刊论文

V-shaped substrate for surface and volume enhanced Raman spectroscopic analysis of microplastics

期刊论文

Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

期刊论文

Solar photovoltaic fed dual input LED lighting system with constant illumination control

Kinattingal SUNDARESWARAN,Kevin Ark KUMAR,Payyalore Raman VENKATESWARAN,Sankaran PALANI

期刊论文

Ternary phase behavior of water microemulsified diesel-palm biodiesel

Nurul Atiqah Izzati MD ISHAK,Ismail Ab RAMAN,Mohd Ambar YARMO,Wan Mohd Faizal WAN MAHMOOD

期刊论文

Large deflection behavior effect in reinforced concrete columns exposed to extreme dynamic loads

MUTALIB, Chunwei ZHANG, Javad MEHRMASHHADI, Sudharshan Naidu RAMAN, Roozbeh ALIPOUR, Tohid MOMENI, Mohamed

期刊论文

SERS nanoprobes for bio-application

Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong

期刊论文

Polymorphism and crystal transformation of penicillin sulfoxide

Dingding JING, Yongli WANG, Zhijian CHEN, Lina ZHOU, Jingkang WANG

期刊论文

Usability perceptions and beliefs about smart thermostats by chi-square test, signal detection theory, and fuzzy detection theory in regions of Mexico

Pedro PONCE, Therese PEFFER, Arturo MOLINA

期刊论文

Advances in airborne microorganisms detection using biosensors: A critical review

期刊论文

Recent advances in SERS detection of perchlorate

Jumin Hao, Xiaoguang Meng

期刊论文

A fast antibiotic detection method for simplified pretreatment through spectra-based machine learning

期刊论文

脉冲辐射探测技术

欧阳晓平

期刊论文

Edge detection of steel plates at high temperature using image measurement

Qiong Zhou, Qi An

期刊论文